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TYPES OF REACTIONS
Review!!
Synthesis
Example C + O2
2
OOC +  O OC
OOC
OOCC
C C C C C C C
C
C
C
General: A + B  AB
C
Decomposition
Example: NaCl
3
General: AB  A + B
Cl Na Cl + Na
Single displacement
Example: Zn + CuCl2
4
ZnClCl
Cu +
General: AB + C  AC + B
ClCl
Zn Cu+
Double displacement
Example: MgO + CaS
5
General: AB + CD  AD + CB
SO
Mg Ca
+
OS
Mg Ca
+
Combustion Reaction
• A reaction that releases carbon dioxide and
water
• A hydrocarbon and oxygen combine to form
CO2 and H2O.
CH4 + 2O2  CO2 + 2H2O
General: AB + CD  CO2 + H2O
ACID BASE REACTIONS
Metals, Non-metals & Neutralizations
METALS
Metal + O2  metal oxide + H2O  Base
• Metals react with oxygen to form metal
oxides
• Metal oxides always form solids
• Metal oxides also called basic oxides or basic
anhydrides
• Metal oxides react in water to form bases
Group 1 Metals (Alkali Metals)
• Potassium burns in O2 to make potassium oxide
4K(s) + O2(g) → 2K2O(s)
Group 1 Metals (Alkali Metals)
• Potassium burns in O2 to make potassium oxide
4K(s) + O2(g) → 2K2O(s)
• Potassium oxide dissolves in H2O
K2O(s) + H2O(l) → 2KOH(aq)
Group 1 Metals (Alkali Metals)
• Potassium burns in O2 to make potassium oxide
4K(s) + O2(g) → 2K2O(s)
• Potassium oxide dissolves in H2O
K2O(s) + H2O(l) → 2KOH(aq)
• Alternatively you can add potassium directly to water
2K(s) + 2H2O(l) → 2KOH(aq) + H2(g)
• KOH used to make soap, liquid fertilizer, paint remover,
cosmetics
Synthesis
Single
Displacement
Group 2 Metals (Alkali Earth Metals)
• Formation of Metal oxide
2Ca(s) + O2(g) → 2CaO(s)
• Formation of base
CaO(s) + H2O(l) → Ca(OH)2(aq)
• Lime (CaO) added to soil for growth of plants that prefer
basic soil.
• Ca(OH)2 used in bricks and as a food additive.
Other Metals - Zinc
• Formation of metal oxide:
Zn + O2  ZnO
• Formation of base:
ZnO + H2O  Zn(OH)2
• ZnO is often used as an additive to plastic, glass, cement,
paints, ointments, sealants, foods, batteries and fire
retardants.
• One major use of Zn(OH)2 is as an absorbent in surgical
dressings.
NON-METALS
Non-Metal + O2  N-M oxide + H2O  Acid
• React in O2 to form non-metal oxides
• Non-metal oxides are often fluids (gas/liquid)
• N-M oxides known as acidic oxides
• Non-metal oxides react in water to form
acids
Nitrogen
• Nitrogen reacts with O2 to make nitrogen dioxide
N2(g) + 2O2(g) → 2NO2(g)
• Nitrogen dioxide dissolves in H2O to form nitric acid
3NO2(g) + H2O(l) → 2HNO3(aq) + NO(g)
• Nitrogen dioxide contributes to air pollution.
• Nitric acid can be used in explosives for munitions and
demolition. It can also be used for pigments in inks and
dyes.
Synthesis
Phosphorus
• Formation of Non-Metal oxide
4P(s) + 5O2(g) → 2P2O5(s)
• Formation of acid
P2O5(s) + 3H2O(l) → 2H3PO4(aq)
• Diphosphorus pentoxide is used as a very strong
dehydrating agent.
• Phosphoric acid used to make fertilizers, home cleaning
products and rust inhibitor.
Carbon
• Formation of non-metal oxide:
C + O2  CO2
• Formation of acid:
CO2(g) + H2O(l) → H2CO3(aq)
• Carbon dioxide is produced from the burning of fossil
fuels and contributes to global warming
• Carbonic acids are a major factor in ocean acidification.
NEUTRALIZATION
REACTIONS
Acids + Bases
• The H+ ions from the acid can combine with the OH- ions
from the base
H+
(aq) + OH-
(aq) --> HOH(l)
This process is called Neutralization
the resulting solution is neutral
(because water is set to pH 7)
• The reaction of an acid and a base produces a salt and
water
Acid + Base  Salt + Water
• The reaction of an acid and a base produces a salt and
water
Acid + Base  Salt + Water
2HCl(aq) + Mg(OH)2(s)  MgCl2(aq) + H2O(l)
Stomach acid Antacid No more heartburn!!
• A salt is a compound made up of
oppositely-charged ions
Neutralization = double displacement reactions
Ex. 1) Predict the products, balance the equation, state
chemical names, and classify each as either an acid, base,
salt or water.
__Ca(OH)2 + __H3PO4 
Ex. 1) Predict the products, balance the equation, state
chemical names, and classify each as either an acid, base,
salt or water.
_Ca(OH)2 + _H3PO4  _Ca3(PO4)2 + _H2O
Ex. 1) Predict the products, balance the equation, state
chemical names, and classify each as either an acid, base,
salt or water.
3Ca(OH)2 + 2H3PO4  Ca3(PO4)2 + 6H2O
Ex. 1) Predict the products, balance the equation, state
chemical names, and classify each as either an acid, base,
salt or water.
3Ca(OH)2 + 2H3PO4  Ca3(PO4)2 + 6H2O
Calcium hydroxide + phosphoric acid  calcium phosphate + water
Ex. 1) Predict the products, balance the equation, state
chemical names, and classify each as either an acid, base,
salt or water.
3Ca(OH)2 + 2H3PO4  Ca3(PO4)2 + 6H2O
Calcium hydroxide + phosphoric acid  calcium phosphate + water
Base + Acid  Salt + Water
Ex. 2) In there is an industrial accident, a whole barrel of
sulfuric acid (a dangerously strong acid) was spilled. Show
putting a strong base, such as calcium hydroxide, can
neutralize the acid.
Sulfuric acid + calcium hydroxide 
Ex. 2) In there is an industrial accident, a whole barrel of
sulfuric acid (a dangerously strong acid) was spilled. Show
putting a strong base, such as calcium hydroxide, can
neutralize the acid.
Sulfuric acid + calcium hydroxide  calcium sulfate + water
Ex. 2) In there is an industrial accident, a whole barrel of
sulfuric acid (a dangerously strong acid) was spilled. Show
putting a strong base, such as calcium hydroxide, can
neutralize the acid.
Sulfuric acid + calcium hydroxide  calcium sulfate + water
H2SO4(aq) + Ca(OH)2(aq)  CaSO4(s) + 2H2O(l)

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3 acid base reactions

  • 2. Synthesis Example C + O2 2 OOC +  O OC OOC OOCC C C C C C C C C C C General: A + B  AB C
  • 3. Decomposition Example: NaCl 3 General: AB  A + B Cl Na Cl + Na
  • 4. Single displacement Example: Zn + CuCl2 4 ZnClCl Cu + General: AB + C  AC + B ClCl Zn Cu+
  • 5. Double displacement Example: MgO + CaS 5 General: AB + CD  AD + CB SO Mg Ca + OS Mg Ca +
  • 6. Combustion Reaction • A reaction that releases carbon dioxide and water • A hydrocarbon and oxygen combine to form CO2 and H2O. CH4 + 2O2  CO2 + 2H2O General: AB + CD  CO2 + H2O
  • 7. ACID BASE REACTIONS Metals, Non-metals & Neutralizations
  • 9. Metal + O2  metal oxide + H2O  Base • Metals react with oxygen to form metal oxides • Metal oxides always form solids • Metal oxides also called basic oxides or basic anhydrides • Metal oxides react in water to form bases
  • 10. Group 1 Metals (Alkali Metals) • Potassium burns in O2 to make potassium oxide 4K(s) + O2(g) → 2K2O(s)
  • 11. Group 1 Metals (Alkali Metals) • Potassium burns in O2 to make potassium oxide 4K(s) + O2(g) → 2K2O(s) • Potassium oxide dissolves in H2O K2O(s) + H2O(l) → 2KOH(aq)
  • 12. Group 1 Metals (Alkali Metals) • Potassium burns in O2 to make potassium oxide 4K(s) + O2(g) → 2K2O(s) • Potassium oxide dissolves in H2O K2O(s) + H2O(l) → 2KOH(aq) • Alternatively you can add potassium directly to water 2K(s) + 2H2O(l) → 2KOH(aq) + H2(g) • KOH used to make soap, liquid fertilizer, paint remover, cosmetics Synthesis Single Displacement
  • 13. Group 2 Metals (Alkali Earth Metals) • Formation of Metal oxide 2Ca(s) + O2(g) → 2CaO(s) • Formation of base CaO(s) + H2O(l) → Ca(OH)2(aq) • Lime (CaO) added to soil for growth of plants that prefer basic soil. • Ca(OH)2 used in bricks and as a food additive.
  • 14. Other Metals - Zinc • Formation of metal oxide: Zn + O2  ZnO • Formation of base: ZnO + H2O  Zn(OH)2 • ZnO is often used as an additive to plastic, glass, cement, paints, ointments, sealants, foods, batteries and fire retardants. • One major use of Zn(OH)2 is as an absorbent in surgical dressings.
  • 16. Non-Metal + O2  N-M oxide + H2O  Acid • React in O2 to form non-metal oxides • Non-metal oxides are often fluids (gas/liquid) • N-M oxides known as acidic oxides • Non-metal oxides react in water to form acids
  • 17. Nitrogen • Nitrogen reacts with O2 to make nitrogen dioxide N2(g) + 2O2(g) → 2NO2(g) • Nitrogen dioxide dissolves in H2O to form nitric acid 3NO2(g) + H2O(l) → 2HNO3(aq) + NO(g) • Nitrogen dioxide contributes to air pollution. • Nitric acid can be used in explosives for munitions and demolition. It can also be used for pigments in inks and dyes. Synthesis
  • 18. Phosphorus • Formation of Non-Metal oxide 4P(s) + 5O2(g) → 2P2O5(s) • Formation of acid P2O5(s) + 3H2O(l) → 2H3PO4(aq) • Diphosphorus pentoxide is used as a very strong dehydrating agent. • Phosphoric acid used to make fertilizers, home cleaning products and rust inhibitor.
  • 19. Carbon • Formation of non-metal oxide: C + O2  CO2 • Formation of acid: CO2(g) + H2O(l) → H2CO3(aq) • Carbon dioxide is produced from the burning of fossil fuels and contributes to global warming • Carbonic acids are a major factor in ocean acidification.
  • 21. Acids + Bases • The H+ ions from the acid can combine with the OH- ions from the base H+ (aq) + OH- (aq) --> HOH(l) This process is called Neutralization the resulting solution is neutral (because water is set to pH 7)
  • 22. • The reaction of an acid and a base produces a salt and water Acid + Base  Salt + Water
  • 23. • The reaction of an acid and a base produces a salt and water Acid + Base  Salt + Water 2HCl(aq) + Mg(OH)2(s)  MgCl2(aq) + H2O(l) Stomach acid Antacid No more heartburn!!
  • 24. • A salt is a compound made up of oppositely-charged ions Neutralization = double displacement reactions
  • 25. Ex. 1) Predict the products, balance the equation, state chemical names, and classify each as either an acid, base, salt or water. __Ca(OH)2 + __H3PO4 
  • 26. Ex. 1) Predict the products, balance the equation, state chemical names, and classify each as either an acid, base, salt or water. _Ca(OH)2 + _H3PO4  _Ca3(PO4)2 + _H2O
  • 27. Ex. 1) Predict the products, balance the equation, state chemical names, and classify each as either an acid, base, salt or water. 3Ca(OH)2 + 2H3PO4  Ca3(PO4)2 + 6H2O
  • 28. Ex. 1) Predict the products, balance the equation, state chemical names, and classify each as either an acid, base, salt or water. 3Ca(OH)2 + 2H3PO4  Ca3(PO4)2 + 6H2O Calcium hydroxide + phosphoric acid  calcium phosphate + water
  • 29. Ex. 1) Predict the products, balance the equation, state chemical names, and classify each as either an acid, base, salt or water. 3Ca(OH)2 + 2H3PO4  Ca3(PO4)2 + 6H2O Calcium hydroxide + phosphoric acid  calcium phosphate + water Base + Acid  Salt + Water
  • 30. Ex. 2) In there is an industrial accident, a whole barrel of sulfuric acid (a dangerously strong acid) was spilled. Show putting a strong base, such as calcium hydroxide, can neutralize the acid. Sulfuric acid + calcium hydroxide 
  • 31. Ex. 2) In there is an industrial accident, a whole barrel of sulfuric acid (a dangerously strong acid) was spilled. Show putting a strong base, such as calcium hydroxide, can neutralize the acid. Sulfuric acid + calcium hydroxide  calcium sulfate + water
  • 32. Ex. 2) In there is an industrial accident, a whole barrel of sulfuric acid (a dangerously strong acid) was spilled. Show putting a strong base, such as calcium hydroxide, can neutralize the acid. Sulfuric acid + calcium hydroxide  calcium sulfate + water H2SO4(aq) + Ca(OH)2(aq)  CaSO4(s) + 2H2O(l)